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Biosorption of Cu(II) to extracellular polymeric substances (EPS) from

Xiangliang PAN, Jing LIU, Wenjuan SONG, Daoyong ZHANG

《环境科学与工程前沿（英文）》 2012年第6卷第4期页码 493-497 doi: 10.1007/s11783-012-0416-9

摘要： Biosorption of extracellular polymeric substances (EPS) from sp. (cyanobacterium) with Cu(II) was investigated using fluorescence spectroscopy. Three fluorescence peaks were found in the excitation-emission matrix (EEM) fluorescence spectra of EPS. Fluorescence of peak A (Ex/Em= 275/452 nm) and peak C (Ex/Em= 350/452 nm) were originated from humic-like substances and fluorescence of peak B (Ex/Em= 275/338 nm) was attributed to protein-like substances. Fluorescence of peaks A, B, and C could be quenched by Cu(II). The effective quenching constants (lg K ) were 2.8–5.84 for peak A, 6.4–9.24 for peak B, and 3.48–6.68 for peak C, respectively. The values of lg K showed a decreasing trend with increasing temperature, indicating that the quenching processes were static in nature. The binding constants (lg K ) followed the order of peak A>peak B>peak C, implying that the humic-like substances in EPS have greater Cu(II) binding capacity than the protein-like substances. The binding site number, , in EPS-Cu(II) complexes for peaks A, B, and C was less than 1. This suggests the negative cooperativity between multiple binding sites and the presence of more than one Cu binding site.

关键词： biosorption conditional binding constant extracellular polymeric substances (EPS) fluorescence quenching

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The biosorption of Cr(VI) ions by dried biomass obtained from a chromium-resistant bacterium

Paul Fabrice NGUEMA,Zejiao LUO,Jingjing LIAN

《化学科学与工程前沿（英文）》 2014年第8卷第4期页码 454-464 doi: 10.1007/s11705-014-1456-4

摘要： The biosorption potential of many different kinds of biomaterials has been widely studied. However, there is little data on the biosorption mechanism of Cr(VI) by dried biomass. So the bio-removal of Cr(VI) ions from aqueous solutions was investigated using dried biomass from a chromium-resistant bacterium. The bacterium was isolated from dewatered sludge samples that were obtained from a sewage treatment plant. Equilibrium and kinetic experiments were performed at different metal concentrations, pH values, and biosorbents dosages. The biomass was characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The functional groups in the biomass which may play a role in the biosorption process were identified by Fourier transform infrared spectroscopy. The biosorption process was found to be highly pH dependent and the optimum pH for the adsorption of Cr(VI) was 2.0±0.3 at 30±2 °C. The experimental data fit well with Langmuir and Freundlich models as well as a pseudo-second order kinetic model. The mechanism for the biosorption was also studied by fitting the kinetic data with an intra-particle diffusion model and a Boyd plot. External mass transfer was found to be the rate-determining step for the adsorption process. Biosorption could be an alternative mechanism besides bio-oxidation and bio-reduction for the bioremediation of heavy metals.

关键词： Cr(VI) biomass Bacillus cereus Pf-1 biosorption capacity biosorbents

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Biosorption of mercury and lead by aqueous

Pratibha SANJENBAM, Kumar SAURAV, Krishnan KANNABIRAN

《化学科学与工程前沿（英文）》 2012年第6卷第2期页码 198-202 doi: 10.1007/s11705-012-1285-2

摘要： Toxic heavy metals are increasingly accumulating in the environment worldwide and are considered to be life threatening contaminants. The biosorption of mercury and lead by marine actinomycetes isolated from marine sediment collected from the Bay of Bengal coast of Puducherry, India, was evaluated. The maximum tolerance concentration (MTC) of sp. was determined by a well diffusion method and a broth dilution method. The effects of the initial metal ion concentration, the pH and the biomass dosage on the biosorption of mercury and lead ions were investigated. The MTC of the isolate to metals was 200 mg·L for mercury and 1800 mg·L for lead. At neutral pH, the isolate had a maximum biosorption of metal ions of 200 mg·L and 150 mg·L for mercury and lead respectively. Fourier transform infrared (FTIR) absorption spectra showed the chemical interactions between the functional groups in the biomass such as hydroxyl (-OH), amine (-NH ), carboxyl (-COOH) and the metal ions. The isolate was further characterized by molecular taxonomy and identified as a member of the genus Based on the phenotypic and phylogenetic analysis, the strain was classified as a new species of the genus and designated as VITSVK9 sp. (HM137310). A blast search of the 16S rDNA sequence of the strain showed the most similarity (95%) with sp. A515 Ydz-FQ (EU384279). Based on the results, it can be concluded that this marine could be used as a biosorbent for the removal of heavy metal ions from aqueous environments.

关键词： mercury lead biosorption maximum tolerance concentration Streptomyces VITSVK9 sp.

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Biosorption and biotransformation of crystal violet by

Tao PAN, Suizhou REN, Jun GUO, Meiying XU, Guoping SUN

《环境科学与工程前沿（英文）》 2013年第7卷第2期页码 185-190 doi: 10.1007/s11783-012-0435-6

摘要： DN322p, an offspring of DN322, has the capacity to adsorb and decolorize triphenylmethane dyes in wastewater simultaneously. As a common triphenylmethane dye, crystal violet (CV) was chosen to test the decolorization characteristics of DN322p. Within 0.5 h, the strain DN322p adsorbed a large amount of CV, producing a deep-colored cell pellet and colorless supernatant. The colors of the cell pellet and supernatant lightened over time. The supernatant and dichloromethane extract of the cell pellet both showed conspicuous CV and leuco CV (LCV) characteristic absorbance peaks at 590 nm and 260 nm, respectively, in the UV-vis spectral analysis. This finding indicated that the DN322p cells can adsorb the two dyes. A 99% (w/w) decolorization rate was achieved within 2.5 h with shaking at 30°C for 50 mg CV·L . High Performance Liquid Chromatography (HPLC) analysis of the dichloromethane extract of the supernatant and cell pellet confirmed that CV was mainly converted into its leuco form. Dead cells had a similar adsorption capacity with living cells. About 90% of CV in the dye solution (50 mg·L ) was removed by autoclaved cells with an optical delnsity at 600 nm (OD ) above 1.0.

关键词： crystal violet decolorization biosorption biotransformation Aeromonas hydrophila DN322p

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Biosorption of Cd

Fengyu ZAN, Shouliang HUO, Beidou XI, Xiulan ZHAO

《环境科学与工程前沿（英文）》 2012年第6卷第1期页码 51-58 doi: 10.1007/s11783-011-0206-9

摘要： The biosorption of Cd and Cu onto the immobilized ( ) was investigated in this study. Adsorption kinetics, isotherms and the effect of pH were studied. The results indicated that the biosorption of Cd and Cu on the immobilized was fast at initial stage and then became slow. The maximum biosorption of heavy metal ions on immobilized were observed at pH 4 for Cd and Cu . by the pseudo-second-order model described the sorption kinetic data well according to the high correlation coefficient ( ) obtained. The biosorption isotherm was fitted well by the Langmuir model, indicating possible mono-layer biosorption of Cd and Cu on the immobilized . Moreover, the immobilized after the sorption of Cd and Cu could be regenerated and reused.

关键词： Saccharomyces cerevisiae (S. cerevisiae) biosorption heavy metals immobilization desorption

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Biosorption of Cr(VI) by carbonized

Jinfa CHEN,Ping YANG,Dagang SONG,Sha YANG,Li ZHOU,Lei HAN,Bo LAI

《环境科学与工程前沿（英文）》 2014年第8卷第6期页码 960-966 doi: 10.1007/s11783-013-0612-2

摘要： High quality and low cost carbon can be prepared from ( ) and Buckwheat straw. The biosorbent was used for Cr(VI) removal. The effect of experimental parameters, such as pH, sorbent dosage and temperature were examined and the optimal experimental condition was determined. Solution pH is found influencing the adsorption. Cr(VI) removal efficiency is found to be maximum (98%) at pH= 1. Langmuir and Freundlich adsorption isotherms were applicable to the adsorption process and their constants were evaluated. The adsorption data obtained agreed well with the Langmuir sorption isotherm model. The maximum adsorption capacities for Cr(VI) ranged from 46.23 to 55.19 mg·g for temperature between 298 K and 308 K under the condition of pH= 1.0. Thermodynamic parameters such as free energy change ( ), enthalpy ( ) and entropy ( ) indicate a spontaneous, endothermic and increased randomness nature of Cr(VI) adsorption. Studies found that the raw and buckwheat straw mixed materials with simple treatment had a high efficiency for the removal of Cr(VI) and would be a promising adsorbent.

关键词： Eupatorium adenophorum buckwheat straw adsorption Cr(VI) thermodynamics

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Biosorption of Cr(III) from aqueous solution by freeze-dried activated sludge: Equilibrium, kinetic and

Qian YAO, Hua ZHANG, Jun WU, Liming SHAO, Pinjing HE,

《环境科学与工程前沿（英文）》 2010年第4卷第3期页码 286-294 doi: 10.1007/s11783-010-0025-4

摘要： Batch biosorption experiments were conducted to remove Cr(III) from aqueous solutions using activated sludge from a sewage treatment plant. An investigation was conducted on the effects of the initial pH, contact time, temperature, and initial Cr(III) concentration in the biosorption process. The results revealed that the activated sludge exhibited the highest Cr(III) uptake capacity (120 mg·g) at 45°C, initial pH of 4, and initial Cr(III) concentration of 100 mg·L. The biosorption results obtained at various temperatures showed that the biosorption pattern accurately followed the Langmuir model. The calculated thermodynamic parameters, Δ (−0.8– −4.58 kJ·mol), Δ (15.6–44.4 kJ·mol), and Δ (0.06–0.15 kJ·mol·K) clearly indicated that the biosorption process was feasible, spontaneous, endothermic, and physical. The pseudo first-order and second-order kinetic models were adopted to describe the experimental data, which revealed that the Cr(III) biosorption process conformed to the second-order rate expression and the biosorption rate constants decreased with increasing Cr(III) concentration. The analysis of the values of biosorption activation energy ( = −7 kJ·mol) and the intra-particle diffusion model demonstrated that Cr(III) biosorption was film-diffusion-controlled.

关键词： activated sludge biosorption chromium film diffusion kinetics thermodynamics

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Biosorption of Direct Black 38 by dried anaerobic granular sludge

WANG Xuejiang, XIA Siqing, ZHAO Jianfu

《环境科学与工程前沿（英文）》 2008年第2卷第2期页码 198-202 doi: 10.1007/s11783-008-0031-y

摘要： The biosorption of Direct Black 38 by dried anaerobic granular sludge in a batch system under specific temperatures and initial pH was investigated. The adsorption reaction is pH dependent with higher removal at low pH. The adsorption equilibrium data fit very well with both Langmuir and Freundlich models in the concentration range of Direct Black 38 at all chosen temperatures. The adsorption parameters show that the adsorption of Direct Black 38 is an endothermic and more effective process at high temperatures. The kinetics of adsorption was found to be second order and adsorption rate constants increased with increasing temperature. Activation energy was determined as 26.8 kJ/mol for the process. This suggests that the adsorption of Direct Black 38 by dried anaerobic granular sludge is chemically controlled.

关键词： Langmuir kJ/mol temperature removal Freundlich

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Removal of Zn

Feng XUE, Beicheng XIA, Rongrong YING, Shili SHEN, Peng ZHAO

《环境科学与工程前沿（英文）》 2013年第7卷第4期页码 531-538 doi: 10.1007/s11783-013-0506-3

摘要： Biosorption of Zn from aqueous solutions by biomass of was investigated. The removal rates of Zn by under different parameters (e.g., solution pH, bio-sorbent dosage and initial Zn concentration) were studied. The inhibition of ’s biosorption by anionic ligands EDTA (Ethylene Diamine Tetraacetic Acid), acetate and citrate) implied that EDTA and citrate might be used as eluting reagents. Regular and simultaneous solution pH change and light metal ions release after biosorption indicated that an ion exchange mechanism was involved. From FT-IR (Fourier Transform Infrared) spectroscopy, the main functional groups participated in biosorption were found. Biosorption of Zn by could be well described by the Freundlich and Langmuir models. In conclusion, the biomass of showed high potential for the treatment of wastewater containing Zn .

关键词： biosorption Agaricus bisporus zinc ion exchange FT-IR isotherms

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Removal of dyes from wastewater by growing fungal pellets in a semi-continuous mode

Tao Lu, Qilei Zhang, Shanjing Yao

《化学科学与工程前沿（英文）》 2017年第11卷第3期页码 338-345 doi: 10.1007/s11705-017-1644-0

摘要： To increase the efficiency of dye removal from wastewater using mycelial pellets, a bubble column reactor with a simple structure was designed and efficiently used to remove dyes from solution containing dyes. The mycelial pellets were prepared by marine fungus ZJUBE-1. Eight dyes were tested as dye targets for the adsorption capacity of mycelial pellets and good removal results were obtained. Eriochrome black T was selected as a model dye for characterizing the adsorption processes in detail. The measurement results of Zeta potential and FT-IR analysis indicate that the electrostatic attraction may play a key role in the biosorption process. The bubble column reactor was utilized to study the batch dye-removal efficiency of mycelial pellets. A re-culture process between every two batches, which was under non-sterile condition, successfully enhanced the utilization of mycelium biomass. The dye removal rate is 96.4% after 12 h in the first batch and then decreases slowly in the following batches. This semi-continuous mode, which consists of commutative processes of dye-removal and re-culture, has some outstanding advantages, such as low power consumption, easy operation, high dye removal rate, and efficient biomass utilization.

关键词： dye mycelial pellets marine fungus bubble column reactor semi-continuous biosorption

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Removal of Cu(II) and Fe(III) from aqueous solutions by dead sulfate reducing bacteria

Hong’en QUAN, He BAI, Yang HAN, Yong KANG, Jiao SUN

《化学科学与工程前沿（英文）》 2013年第7卷第2期页码 177-184 doi: 10.1007/s11705-013-1324-7

摘要： The biosorption properties of dead sulfate reducing bacteria (SRB) for the removal of Cu(II) and Fe(III) from aqueous solutions was studied. The effects of the biosorbent concentration, the initial pH value and the temperature on the biosorption of Cu(II) and Fe(III) by the SRB were investigated. FTIR analysis verified that the hydroxyl, carbonyl and amine functional groups of the SRB biosorbent were involved in the biosorption process. For both Cu(II) and Fe(III), an increase in the SRB biosorbent concentration resulted in an increase in the removal percentage but a decrease in the amount of specific metal biosorption. The maximum specific metal biosorption was 93.25 mg?g at pH 4.5 for Cu(II) and 88.29 mg?g at pH 3.5 for Fe(III). The temperature did not have a significant effect on biosorption. In a binary metal system, the specific biosorption capacity for the target metal decreased when another metal ion was added. For both the single metal and binary metal systems, the biosorption of Cu(II) and Fe(III) onto a SRB biosorbent was better represented by a Langmuir model than by a Freundlich model.

关键词： sulfate reducing bacteria biosorption Cu(II) Fe(III)

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Brown marine algae turbinaria conoides as biosorbent for Malachite green removal: Equilibrium and kinetic modeling

R. RAJESH KANNAN, M. RAJASIMMAN, N. RAJAMOHAN, B. SIVAPRAKASH,

《环境科学与工程前沿（英文）》 2010年第4卷第1期页码 116-122 doi: 10.1007/s11783-010-0006-7

摘要： In this study, the biosorption of Malachite green (MG) onto Turbinaria conoides, brown marine algae, was studied with respect to initial pH, temperature, initial dye concentration, and sorbent dosage. The optimum initial pH and temperature values for MG removal were found to be 8.0 and 30°C, respectively. Sorbent dosage was found to strongly influence the removal of MG. Equilibrium studies were carried out to test the validity of the Langmuir ( = 66.6 mg/g and = 0.526 mL mol/L) and the Freundlich ( = 1.826 and = 3.751 mg/g) isotherms. The kinetic studies indicated the validity of the pseudo first-order and second-order equation.

关键词： Malachite green (MG) Turbinaria conoides marine algae equilibrium studies biosorption